IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND
| Trade name: |
Fischer Injection Mortar FIS P 380 C |
| Typical application: |
Heavy duty anchoring free of expansion pressure |
| Manufacturer/supplier: |
Artur Fischer UK Limited |
| Emergency information: |
0049 7443/12-4444 |
COMPOSITION / INFORMATION ON INGREDIENTS:
Component A:
A.2.1 Chemical characterization: Formulation of methacrylates and cement
A.2.2 Dangerous components:
| CAS – No. |
EWG-No |
Material |
Content [%] |
Symbol |
R-Phrases |
| 27813-02-1 |
--- |
2-Hydroxypropylmethacrylate |
< 10 |
Xi |
36, 43 |
| 65997-15-1 |
--- |
Portlandcement CEMI 52,5 SW |
< 10 |
Xi |
38, 41 |
Component B:
B.2.1 Chemical characterization: Formulation of dibenzoyl peroxide, phlegmatised
B.2.2 Dangerous components:
| CAS – No. |
EWG-No |
Material |
Content [%] |
Symbol |
R- Phrases |
| 94-36-0 |
202-327-6 |
Dibenzoyl peroxide, phlegmatised |
< 25 |
E, Xi |
2, 7, 36, 43 |
HAZARDS IDENTIFICATION:
3.1 Hazard description:
| A, B |
Xi |
Irritant |
| B |
O |
Oxidising |
3.2 Information pertaining to particular dangers for man and environment:
| B |
R 7 |
May cause fire. |
| A, B |
R 36 |
Irritating to eyes. |
| A, B |
R 43 |
May cause sensitization by skin contact. |
FIRST AID MEASURES:
| General information: |
Remove contaminated clothing. |
| After inhalation: |
Rest, fresh air. |
| After skin contact: |
Rinse thoroughly using water and soap. |
| After eye contact: |
Open lid and thoroughly flush for 10 – 15 minutes using clean water. Consult a doctor. |
| After swallowing: |
Immediately rinse out the mouth. DO NOT induce vomiting. Consult a doctor. |
| Indications for the doctor: |
None. |
FIRE FIGHTING MEASURES
| Suitable extinguishing media: |
Spray water, foam, dry powder extinguisher, carbon dioxide (CO2). |
| For safety reasons unsuitable extinguishing media: |
Water applied with full jet. |
| Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases: |
Fire may release carbon monoxide (CO) and carbon dioxide (CO2). |
| Special protective equipment for fire fighting |
Use breathing apparatus with independent air supply. |
| Other information: |
None. |
ACCIDENTAL RELEASE MEASURES
| Person-related safety precautions: |
Move all persons out of the hazard area |
| Measures for environmental protection: |
Do not allow to reach open waters, sewers or water pipes. |
| Measures for cleaning/absorption: |
Use-liquid-binding material (e.g. sand, dry earth) to soak up. Take up solids by mechanical means. Fill into sealable and labelled containers and dispose as described in chapter 13. |
| Other information: |
None. |
HANDLING AND STORAGE
Handling:
| Information for safe handling: |
Use only in well ventilated work areas. Avoid direct exposure to sunlight. Maximum temperature (short-term) 35 ºC, minimum temperature 0 °C. |
| Information about protection against explosions and fires: |
Keep product away from heat sources, open fires, etc., do not smoke. |
Storage:
| Requirements to be met by storerooms and receptables: |
Keep cartridge tightly sealed in its original package and store in a dry, cool (max. 25 ºC) and well ventilated place. |
| Rules for the mixed storage of chemicals: |
Do not store together with combustible substances. |
| Further information about storage conditions: |
Keep dry. |
| Storage class: |
5.2 according to VCI guideline. |
EXPOSURE CONTROLS / PERSONAL PROTECTION:
Additional information about design of technical systems:
No further information. See chapter 7.
Components with limit values that require monitoring at the workplace:
| CAS – No. |
Material |
Content[%] |
Type |
mg/m³ |
ppm |
Fibre/m³(F/G) |
|
-
|
-
|
-
|
-
|
-
|
-
|
-
|
Additional information:
None
Personal protective equipment:
| Respiratory protection |
Not required. |
| Hand protection: |
Wear suitable protective gloves made of nitrile. See EN 374. |
| Eye protection: |
Tight-fitting safety goggles. See EN 166 F. |
| Body protection: |
Wear closed working clothes. |
| General protective and hygienic measures: |
Do not eat, drink or smoke while working. Immediately remove Contaminated clothes. Protect skin with protective skin cream. Avoid contact with skin, eyes and clothes. |
PHYSICAL AND CHEMICAL PROPERTIES:
| Appearance: |
Component A |
Component B |
| Form: |
Paste |
Paste |
| Colour: |
Light grey |
Dark grey |
| Odour: |
Characteristic |
Weak |
| Safety parameters: |
Component A |
Component B |
Method: |
| ph - Value at ... g/l H2O; ... °C |
| Change in condition: |
| Boiling point/boiling range: |
°C |
°C |
|
| Melting point/melting range: |
< - 20 °C |
approx.. 0 °C |
|
| Oxidizing properties |
-
|
Yes |
|
| Danger of explosion: |
No |
No |
|
| Vapour pressure:at ... °C |
hPa |
hPa |
|
| Density: at 20 °C |
1.8 g/cm³ |
1.6 g/cm³ |
|
| Viscosity: at 20 °C |
900000-1500000 mPa s |
800000-1200000 mPa s |
Brookfield Sp 7 0.5 rpm |
| Solvent content |
% |
% |
|
| Further information: |
--- |
|
|
STABILITY AND REACTIVITY:
| Conditions to be avoided: |
Direct exposure to sunlight and temperatures exceeding 35 ºC. |
| Materials to be avoided: |
None known, if cartridge is not damaged. |
| Hazardous decomposition products: |
None, if used as specified. |
| Further information: |
Heat development during polymerization. |
TOXICOLOGICAL INFORMATION:
| Acute toxicity: LD50/LC50 values which are relevant for classification: |
The product has not been tested. |
| Specific symptoms in animal studies: |
The product has not been tested. |
| Irritant effects: |
The product has not been tested. |
| Sensitization: |
The product has not been tested. |
| Effects after repeated or longtime Exposition: |
The product has not been tested. |
| Carcinogenic, mutagenic, teratogenic or dangerous effects on fertility: |
No. |
| Further toxicological information: |
Classification made in accordance with the method of determination specified in the formulation directive (1999/45/EG). |
ECOLOGICAL INFORMATION:
| Information on elimination: (Persistence and degradability): |
No information available. |
| Behaviour in environmental compartiments: |
No information available. |
| Ecotoxicological effects: |
No data available. |
| Further ecological information: |
Do not allow components to reach open waters, sewers or water pipes. |
DISPOSAL CONSIDERATIONS:
Product:
| Recommendation: |
Uncured: Waste material requiring special supervision, to be disposed in compliance with official local regulations (e.g. suitable incineration plant).Cured: May be disposed in compliance with official local regulations as domestic waste. |
| European waste code: |
07 02 08 |
Contaminated packaging:
| Recommendation: |
Have to be disposed in compliance with official local regulations (e.g. suitable incineration plant). |
| Recommended cleaning agent: |
Cartridge cannot be cleaned. |
| European waste code: |
15 01 10 |
TRANSPORT INFORMATION:
Land transport ADR/RID/GGVS/GGVE:
Inland navigation ADN/ADNR:
Transport by sea IMDG/GGVSea:
Air transport ICAO/IATA:
Remarks: Not considered as dangerous goods‘.
REGULATIONS
Labelling according to EC Directives/Gefahrstoffverordnung:
Component A:
Hazard-determing component(s) for labelling:
Contains: 2-Hydroxypropylmethacrylate, Portland cement
R-Phrase:
| R 36 |
Irritating to eyes. |
| R 43 |
May cause sensitization by skin contact. |
S-Phrases:
| S 24 |
Avoid contact with skin. |
| S 26 |
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| S 36/37/39 |
Wear suitable protective clothing, gloves and eye/face protection. |
Component B:
Hazard-determing component(s) for labelling:
Contains: Dibenzoyl peroxide
R-Phrases:
| R 7 |
May cause fire. |
| R 36 |
Irritating to eyes. |
| R 43 |
May cause sensitization by skin contact. |
S-Phrases:
| S 3 |
Keep in a cool place. |
| S 14 |
Keep away from reducing substances, acids, alkalies and heavy metal compounds. |
| S 24 |
Avoid contact with skin. |
| S 26 |
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| S 37/39 |
Wear suitable gloves and eye/face protection. |
Special designations for certain preparations: ---
National regulations (Germany):
Indications for employment control: Observe § 2 Jugendarbeitsschutzgesetz
Regulations for incidents:
Classification according to VbF: n.s.
Technical instructions (Air):
Water hazard class: 1 (VwVwS)
Further regulations:
Limitations and prohibition regulations:
OTHER INFORMATION:
Further information:
The above information describes exclusively the safety requirements of the product(s) and is based on our present knowlegde. It does not represent a guarantee for the properties of the product(s) described in terms of the legal warranty regulations. Properties of the product are to be found in the repective product leaflet.
Department issuing MSDS: Department BT-C (Environment and Safety)fischer Group of companies, location Denzlingen