1. Identification of the substance/preparation and company
| Trade name: |
Fischer Eurobond FEB RM resin capsule |
| Typical application: |
Heavy duty anchoring free of expansion pressure |
| Manufacturer: |
Artur Fischer UK Limited |
| Emergency information: |
0049 7443/12-4444 |
2. Composition/information on ingredients
Component A:
A.2.1 Chemical characterization: Formulation of methacrylates and mineral fillers
A.2.2 Dangerous components:
| CAS – No |
EWG-No |
Material
|
Content -% |
Symbol |
R-Phrases |
| --- |
--- |
607-134-00-4 |
Methacrylate |
< 25 |
Xi |
36/37/38, 43 |
Component B:
B.2.1 Chemical characterization: Formulation of dibenzoyl peroxide, phlegmatised
B.2.2 Dangerous components:
| CAS – No |
EWG-No |
Material
|
Content -% |
Symbol |
R-Phrases |
| 94-36-0 |
202-327-6 |
Dibenzoyl peroxide, phlegmatised |
< 17 |
E, Xi |
2/7/36/43 |
3. Hazards identifaction
3.1 Hazard description:
| A |
Xi |
Irritant |
| B |
O |
Oxidising |
3.2 Information pertaining to particular dangers for man and environment:
| A |
R 36/3738 |
Irritating to eyes, respiratory system and skin. |
| B |
R 7 |
May cause fire. |
| A, B |
R 43 |
May cause sensitization by skin contact. |
4. First aid measures
| General information: |
Remove contaminated clothing. |
| After inhalation: |
Rest, fresh air. |
| After skin contact: |
Rinse thoroughly using water and soap. |
| After eye contact: |
Open lid and thoroughly flush for 10 – 15 minutes using clean water. Avoid mechanical irritation by rubbing the eyes. Consult a doctor. |
| After swallowing: |
Immediately rinse out the mouth. Consult a doctor. |
| Indications for the doctor: |
None. |
5. Fire-fighting measures
| Suitable extinguishing media: |
Spray water, foam, dry powder extinguisher, carbon dioxide (CO2). |
| For safety reasons unsuitable extinguishing media: |
Water applied with full jet. |
| Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases: |
Fire may release carbon monoxide (CO) and carbon dioxide (CO2). |
| Special protective equipment for fire fighting: |
Use breathing apparatus with independent air supply. |
| Other information: |
None. |
6. Accidental release measures
| Person-related safety precautions: |
Move all persons out of the hazard area. |
| Measures for environmental protection: |
Do not allow to reach open waters, sewers or water pipes |
| Measures for cleaning/absorption: |
Use-liquid-binding material (e.g. sand, dry earth) to soak up. Take up solids by mechanical means. Fill into sealable and labelled containers and dispose as described in chapter 13. |
| Other information: |
None. |
7. Handling and storage
Handling:
| Information for safe handling: |
Use only in well ventilated work areas. Avoid direct exposure to sunlight. Maximum temperature (short-term) 35 ºC, minimum temperature 0 ºC. |
| Information about protection against explosions and fires: |
Keep product away from heat sources, open fires, etc., do not smoke. |
Storage:
| Requirements to be met by storerooms and receptables: |
Keep capsule in its original package and store in a dry, cool (max. 25 ºC) and well ventilated place. |
| Rules for the mixed storage of chemicals: |
Do not store together with combustible substances. |
| Further information about storage conditions: |
Keep dry. |
| Storage class: |
5.2 according to VCI guideline. |
8. Exposure controls and personal protection
Additional information about design of technical systems:
No further information. See chapter 7.
Components with limit values that require monitoring at the workplace:
| CAS – No |
Material |
Content[%] |
Type |
mg/m³ |
ppm |
Fibre/m³(F/G) |
| 94-36-0 |
Dibenzoyl peroxide, phlegmatised |
< 17 |
MAK |
5 E |
-
|
|
Additional information:
---
Personal protective equipment:
| Respiratory protection: |
Not required. |
| Hand protection: |
Wear suitable protective gloves made of nitrile. See EN 374. |
| Eye protection: |
Tight-fitting safety goggles. See EN 166 F. |
| Body protection: |
Wear closed working clothes. |
| General protective and hygienic measures: |
Do not eat, drink or smoke while working. Immediately remove Contaminated clothes. Protect skin with protective skin cream. Avoid contact with skin, eyes and clothes.
|
9. Physical and chemical properties
| Appearance: |
Component A |
Component B |
| Form: |
Inhomogene, solid and liquid components |
Capsule of glass, containing powder components |
| Colour: |
Clear |
White |
| Odour: |
Weak |
Odourless |
| Safety parameters: |
Component A Liquid components |
Component B Powder components |
Method: |
| ph - Value at ... g/l H2O; ... °C |
Acid content < 0.5 mg/g KOH |
7 |
|
| Change in condition: |
|
|
|
| Boiling point/boiling range: |
Polymerization >114 °C |
n.d. |
| Melting point/melting range: |
< - 20 °C |
Ca. 55°C |
| Flash point: |
> 200 °C |
n.a. |
Cleveland, open pot |
| Inflammability:(Solid): |
- |
n.d |
|
| Ignition temperature |
- |
n.d |
|
| Self igniting: |
> 400 °C |
The product is not self igniting |
|
| Oxidizing properties: |
No |
Yes |
|
| Danger of explosion: |
n.d |
No |
|
| Explosion limits: |
|
|
|
| LEL: |
n.d |
- |
| UEL: |
n.d |
- |
|
| Vapour pressure: at 20 °C |
n.d. |
n.d. |
|
| Density: at 20 °C |
1.12 – 1.13 g/cm³ |
1.1 g/cm³ |
|
| Solubility: |
|
|
|
| Water: at 20 °C |
Unsoluble |
Unsoluble |
| Organic solvents: at 20 °C |
Soluble in the most organic solvents |
Acetone |
Partition coefficient n-Octanol/Water (log pOW): |
n.d. |
n.d. |
|
Viscosity: at 25 °C |
Ca. 500 mPa s |
n.a. |
|
| Further information: |
|
|
|
| Bulk density at 20 °C |
- |
688 kg/m³ |
|
| Decomposition temperature: |
- |
> + 60 °C (SADT) |
|
Stability and reactivity
| Conditions to be avoided: |
Direct exposure to sunlight and temperatures exceeding 35 ºC. |
| Materials to be avoided: |
Keep away from reducing substances, acids, alkalies and heavy metal compounds. |
| Hazardous decomposition products: |
None, if used as specified. |
| Further information: |
None. |
11. Toxicological information
| Acute toxicity: |
LD50/LC50 values which are relevant for classification: The product has not been tested. |
| Specific symptoms in animal studies: |
The product has not been tested. |
| Irritant effects: |
Irratant effects possible by contact with skin, mucous membrane and eyes. |
| Sensitization: |
Component B, powder material: May cause sensitization by skin contact. |
| Effects after repeated or longtime Exposition: |
--- |
| Carcinogenic, mutagenic, teratogenic or dangerous effects on fertility: |
--- |
| Further toxicological information: |
--- |
12. Ecological information
| Information on elimination: |
(Persistence and degradability)Component A, liquids: Biological not easy degradable.Component B: In water stable. Can be removed from the water mechanically. |
| Behaviour in environmental compartiments: |
The product has not been tested. |
| Ecotoxicological effects: |
The product has not been tested. |
| Further ecological information: |
Water hazard class: 1 |
13. Disposal consideration
Product:
| Recommendation: |
Waste material requiring special supervision, to be disposed in compliance with official local regulations (e.g. suitable incineration plant). |
| European waste code: |
07 02 08 |
Contaminated packaging:
| Recommendation: |
--- |
| Recommended cleaning agent: |
--- |
| European waste code: |
15 01 10 |
| Further information |
--- |
14. Transport information
Land transport ADR/RID/GGVS/GGVE:
| Classification: |
5.2 |
Classification Code: |
P1 |
Warning board Hazard - No. |
- |
UN - No.: |
3106 |
| Description of goods: |
Organic peroxide type D, solid |
| Remarks: |
Limited quantities LQ 11 |
Inland navigation ADN/ADNR:
Transport by sea IMDG/GGVSea:
| IMDG/GGVSea-class : |
5.2 |
UN-No.: |
3106 |
| Packaging Group: |
II |
EmS: |
5.2-01 |
| MFAG: |
735 |
Marine pollutant: |
|
| Correct technical name: |
Organic peroxide type D, solid (contains dibenzoyl peroxide) |
| Remarks: |
Dangerous goods in limited quantities class 5.2, chapter 3.4 |
Air transport ICAO/IATA:
| ICAO/IATA-class: |
5.2 |
UN-No.: |
3106 |
| Packaging Group: |
II |
Label: |
5.2 |
| Correct technical name: |
Organic peroxide type D, solid (contains dibenzoyl peroxide) |
| Remarks: |
Sales packaging units have to be sealed dense against dust with a polyethylene film of minimum thickness 0,1 mm. |
15. Regulations
Labelling according to EC Directives/Gefahrstoffverordnung:
Labelling is based on GefStoffV and directive 1999/45/EG.
Component A:
Hazard-determing component(s) for labelling:
Contains: Methacrylate
R-Phrase:
| R 36/37/38 |
Irritating to eyes, respiratory system and skin. |
| R 43 |
May cause sensitization by skin contact. |
S-Phrases:
| S 3 |
Keep in a cool place. |
| S 26 |
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| S 28 |
After contact with skin, wash immediately with plenty of water and soap. |
| S 37/39 |
Wear suitable gloves and eye/face protection. |
Component B:
Hazard-determing component(s) for labelling:
Contains: Dibenzoyl peroxide
R-Phrases:
| R 7 |
May cause fire. |
| R 43 |
May cause sensitization by skin contact. |
S-Phrases:
| S 3 |
Keep in a cool place. |
| S 14 |
Keep away from reducing substances, acids, alkalies and heavy metal compounds. |
| S 26 |
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| S 28 |
After contact with skin, wash immediately with plenty of water and soap. |
| S 37/39 |
Wear suitable gloves and eye/face protection. |
16. Other information
Further information:
The above information describes exclusively the safety requirements of the product(s) and is based on our present knowlegde. It does not represent a guarantee for the properties of the product(s) described in terms of the legal warranty regulations. Properties of the product are to be found in the repective product leaflet