RM Eurobond Resin Capsules

 

 

 

 

 

 

1. Identification of the substance/preparation and company

Trade name: Fischer Eurobond FEB RM resin capsule
Typical application: Heavy duty anchoring free of expansion pressure
Manufacturer: Artur Fischer UK Limited
Emergency information: 0049 7443/12-4444

2. Composition/information on ingredients

Component A:

A.2.1 Chemical characterization: Formulation of methacrylates and mineral fillers

A.2.2 Dangerous components:

CAS – No EWG-No
Material
Content -% Symbol R-Phrases
--- --- 607-134-00-4 Methacrylate < 25 Xi 36/37/38, 43

Component B:

B.2.1 Chemical characterization: Formulation of dibenzoyl peroxide, phlegmatised

B.2.2 Dangerous components:

CAS – No EWG-No
Material
Content -% Symbol R-Phrases
94-36-0 202-327-6 Dibenzoyl peroxide, phlegmatised < 17 E, Xi 2/7/36/43

3. Hazards identifaction

3.1 Hazard description:

A Xi Irritant
B O Oxidising

3.2 Information pertaining to particular dangers for man and environment:

A R 36/3738 Irritating to eyes, respiratory system and skin.
B R 7 May cause fire.
A, B R 43 May cause sensitization by skin contact.

4. First aid measures

General information: Remove contaminated clothing.
After inhalation: Rest, fresh air.
After skin contact: Rinse thoroughly using water and soap.
After eye contact: Open lid and thoroughly flush for 10 – 15 minutes using clean water. Avoid mechanical irritation by rubbing the eyes. Consult a doctor.
After swallowing: Immediately rinse out the mouth. Consult a doctor.
Indications for the doctor: None.

5. Fire-fighting measures

Suitable extinguishing media: Spray water, foam, dry powder extinguisher, carbon dioxide (CO2).
For safety reasons unsuitable extinguishing media: Water applied with full jet.
Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases: Fire may release carbon monoxide (CO) and carbon dioxide (CO2).
Special protective equipment for fire fighting: Use breathing apparatus with independent air supply.
Other information: None.

6. Accidental release measures

Person-related safety precautions: Move all persons out of the hazard area.
Measures for environmental protection: Do not allow to reach open waters, sewers or water pipes
Measures for cleaning/absorption: Use-liquid-binding material (e.g. sand, dry earth) to soak up. Take up solids by mechanical means. Fill into sealable and labelled containers and dispose as described in chapter 13.
Other information: None.

7. Handling and storage

Handling:

Information for safe handling: Use only in well ventilated work areas. Avoid direct exposure to sunlight. Maximum temperature (short-term) 35 ºC, minimum temperature 0 ºC.
Information about protection against explosions and fires: Keep product away from heat sources, open fires, etc., do not smoke.

Storage:

Requirements to be met by storerooms and receptables: Keep capsule in its original package and store in a dry, cool (max. 25 ºC) and well ventilated place.
Rules for the mixed storage of chemicals: Do not store together with combustible substances.
Further information about storage conditions: Keep dry.
Storage class: 5.2 according to VCI guideline.

8. Exposure controls and personal protection

Additional information about design of technical systems:

No further information. See chapter 7.

Components with limit values that require monitoring at the workplace:

CAS – No Material Content[%] Type mg/m³ ppm Fibre/m³(F/G)
94-36-0 Dibenzoyl peroxide, phlegmatised < 17 MAK 5 E
-


Additional information:


---

Personal protective equipment:

Respiratory protection: Not required.
Hand protection: Wear suitable protective gloves made of nitrile. See EN 374.
Eye protection: Tight-fitting safety goggles. See EN 166 F.
Body protection: Wear closed working clothes.
General protective and hygienic measures:

Do not eat, drink or smoke while working. Immediately remove Contaminated clothes. Protect skin with protective skin cream. Avoid contact with skin, eyes and clothes.

9. Physical and chemical properties

Appearance: Component A Component B
Form: Inhomogene, solid and liquid components Capsule of glass, containing powder components
Colour: Clear White
Odour: Weak Odourless

 

Safety parameters: Component A Liquid components Component B Powder components Method:
ph - Value at ... g/l H2O; ... °C Acid content < 0.5 mg/g KOH 7
Change in condition:
Boiling point/boiling range: Polymerization >114 °C n.d.
Melting point/melting range: < - 20 °C Ca. 55°C
Flash point: > 200 °C n.a. Cleveland, open pot
Inflammability:(Solid): - n.d
Ignition temperature - n.d
Self igniting: > 400 °C The product is not self igniting
Oxidizing properties: No Yes
Danger of explosion: n.d No
Explosion limits:
LEL: n.d -
UEL: n.d -
Vapour pressure: at 20 °C n.d. n.d.
Density: at 20 °C 1.12 – 1.13 g/cm³ 1.1 g/cm³
Solubility:
Water: at 20 °C Unsoluble Unsoluble
Organic solvents: at 20 °C Soluble in the most organic solvents Acetone
Partition coefficient
n-Octanol/Water (log pOW):
n.d. n.d.

Viscosity: at 25 °C
Ca. 500 mPa s
n.a.
Further information:
Bulk density at 20 °C - 688 kg/m³
Decomposition temperature: - > + 60 °C (SADT)

Stability and reactivity

Conditions to be avoided: Direct exposure to sunlight and temperatures exceeding 35 ºC.
Materials to be avoided: Keep away from reducing substances, acids, alkalies and heavy metal compounds.
Hazardous decomposition products: None, if used as specified.
Further information: None.

11. Toxicological information

Acute toxicity: LD50/LC50 values which are relevant for classification: The product has not been tested.
Specific symptoms in animal studies: The product has not been tested.
Irritant effects: Irratant effects possible by contact with skin, mucous membrane and eyes.
Sensitization: Component B, powder material: May cause sensitization by skin contact.
Effects after repeated or longtime Exposition: ---
Carcinogenic, mutagenic, teratogenic or dangerous effects on fertility: ---
Further toxicological information: ---

12. Ecological information

Information on elimination: (Persistence and degradability)Component A, liquids: Biological not easy degradable.Component B: In water stable. Can be removed from the water mechanically.
Behaviour in environmental compartiments: The product has not been tested.
Ecotoxicological effects: The product has not been tested.
Further ecological information: Water hazard class: 1

13. Disposal consideration

Product:

Recommendation: Waste material requiring special supervision, to be disposed in compliance with official local regulations (e.g. suitable incineration plant).
European waste code: 07 02 08

Contaminated packaging:

Recommendation: ---
Recommended cleaning agent: ---
European waste code: 15 01 10
Further information ---


14. Transport information

Land transport ADR/RID/GGVS/GGVE:

Classification: 5.2 Classification Code: P1
Warning board
Hazard - No.
- UN - No.: 3106
Description of goods: Organic peroxide type D, solid
Remarks: Limited quantities LQ 11

Inland navigation ADN/ADNR:

Transport by sea IMDG/GGVSea:

IMDG/GGVSea-class : 5.2 UN-No.: 3106
Packaging Group: II EmS: 5.2-01
MFAG: 735 Marine pollutant:
Correct technical name: Organic peroxide type D, solid (contains dibenzoyl peroxide)
Remarks: Dangerous goods in limited quantities class 5.2, chapter 3.4

Air transport ICAO/IATA:

ICAO/IATA-class: 5.2 UN-No.: 3106
Packaging Group: II Label: 5.2
Correct technical name: Organic peroxide type D, solid (contains dibenzoyl peroxide)
Remarks: Sales packaging units have to be sealed dense against dust with a polyethylene film of minimum thickness 0,1 mm.

15. Regulations

Labelling according to EC Directives/Gefahrstoffverordnung:

Labelling is based on GefStoffV and directive 1999/45/EG.

Component A:

Hazard-determing component(s) for labelling:

Contains: Methacrylate

R-Phrase:

R 36/37/38 Irritating to eyes, respiratory system and skin.
R 43 May cause sensitization by skin contact.

S-Phrases:

S 3 Keep in a cool place.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately with plenty of water and soap.
S 37/39 Wear suitable gloves and eye/face protection.

Component B:

Hazard-determing component(s) for labelling:

Contains: Dibenzoyl peroxide


R-Phrases:

R 7 May cause fire.
R 43 May cause sensitization by skin contact.

S-Phrases:

S 3 Keep in a cool place.
S 14 Keep away from reducing substances, acids, alkalies and heavy metal compounds.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately with plenty of water and soap.
S 37/39 Wear suitable gloves and eye/face protection.

16. Other information

Further information:
The above information describes exclusively the safety requirements of the product(s) and is based on our present knowlegde. It does not represent a guarantee for the properties of the product(s) described in terms of the legal warranty regulations. Properties of the product are to be found in the repective product leaflet

COSHH (05/03)

MATERIAL SAFETY DATA SHEET

RM Resin Capsules